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United States Patent Application

View the Complete Application at the US Patent & Trademark Office
Electrodes useful in dye sensitized photoelectrosynthesis cells provide a coreshell nanoparticle having a chromophore and a catalyst, or a chromophore-catalyst assembly, linked to the shell material. Optionally, an overlayer stabilizes the chromophore or chromophore-catalyst assembly on the shell material. In some embodiments, the core material comprises tin oxide; the shell material comprises titanium dioxide; the chromophore-catalyst assembly includes [(PO.sub.3H.sub.2).sub.2bpy).sub.2Ru(4-Mebpy-4'-bimpy)Ru(tpy) (OH.sub.2)].sup.4+, and the overlayer comprises aluminum oxide or titanium dioxide.
Alibabaei, Leila (Carrboro, NC), Sherman, Benjamin D. (Chapel Hill, NC), Brennaman, M. Kyle (Durham, NC), Meyer, Thomas J. (Chapel Hill, NC)
The University of North Carolina at Chapel Hill (Chapel Hill NC)
15/ 517,233
November 6, 2015
STATEMENT REGARDING FEDERALLY SPONSORED RESEARCH OR DEVELOPMENT [0002] This invention was made with government support under Grant No. DE-SC0001011 awarded by the U.S. Department of Energy. The government has certain rights in the invention.