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NAPL Calculator

Software application that will determine if non-aqueous phase liquid (NAPL) contaminants are present in soil, groundwater, or soil vapor samples

Savannah River National Laboratory

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Technology Marketing Summary

An environmental engineer at the Savannah River Site has developed a software application that will determine if non-aqueous phase liquid (NAPL) contaminants are present in soil, groundwater, or soil vapor samples.  The software will determine both the quantity and composition of NAPL chemicals in the samples based on the results of sample analysis.  The software also computes important environmental engineering measures such as the residual saturation, mass of the NAPL in the sample, and mass balance and phase distribution of each chemical composing the NAPL.

Description

NAPL is an especially detrimental type of environmental contaminant.  It exists in soil or groundwater as the same organic chemical(s) originally shipped from the manufacturer.  Often NAPL comprises different chemicals like trichloroethylene (a solvent) or polychlorinated biphenols (a liquid electrical insulator).  It is extremely difficult to detect in the environment; sometimes its presence must be determined by inferential evidence rather than by direct measurement. 

Failure to recognize the presence of NAPL at a waste site will almost certainly result in failure of clean-up efforts.  It is long lived, has low solubility, and is resistant to many conventional remedial technologies.  Most importantly it will provide a reservoir of contamination for both soil and groundwater on a time scale of 10s to 100s of years.  Therefore, it is absolutely essential that environmental engineers have a tool they can use to assess the nature and severity of NAPL contamination in order to apply and design the correct clean-up technology.

The NAPL Calculator is an analytical model that is a self-executing Microsoft Excel workbook that requires qualitative/quantitative soil, groundwater, or soil vapor sample results and a few simple geotechnical parameters.  A classic chemistry approach is used that is based on the work of Shiu, Feenstra, McKay and Cherry and is advocated by the U.S. Environmental Protection Agency.

The method is known to many academics and researchers but not to many practitioners in environmental clean-up.  Even for those who know the method, the calculation can be laborious.  The NAPL Calculator is designed to make this calculation method accessible, understandable and self-explanatory.

The user selects the chemical(s) detected in the analyses from a pull-down menu, enters the concentrations for those chemicals, and provides some information about soil porosity.  The software contains an imbedded database of physical chemical parameters that it uses to generate a robust body of information that can be used by environmental engineers to assess the level of contamination at a waste site.

   Some of the information the software provides is:

   1.  The existence of NAPL in the samples

   2.  The total mass of NAPL in the samples

   3.  The total mass of NAPL for each chemical composing the NAPL

   4.  The volume of NAPL in the samples (called the residual saturation)

   5.  The concentration and mass of each chemical

   6.  The vapor pressure of the NAPL and of each chemical

   7.  The solubility of the NAPL and of each chemical

   8.  A mass balance and volumetric balance for each chemical

   9.  The percent composition of each chemical

  10.  Automatic graphing of some of the above information 

Benefits
  • easy and quick
  • based on microsoft excel
  • guides clean-up decision making
  • works with soil, soil vapor, or groundwater samples
Technology Status
Technology IDDevelopment StageAvailabilityPublishedLast Updated
SRNL-L9100-2009-00187LicensedLicensed09/26/201209/26/2012

Contact SRNL About This Technology

To: Dale Haas, Commercialization Manager<dale.haas@srnl.doe.gov>