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Wet Chemical Surface Passivation Treatments for CdTe

National Renewable Energy Laboratory

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Technology Marketing Summary

In recent years thin film Cadmium Telluride (CdTe) solar cell recombination rates have been reduced by increasing bulk crystal quality so that a greater number of charge carriers can participate in conduction. As devices have improved and more minority carriers reach the back surface contact layers, surface recombination has become a greater limiter of device efficiency. This inefficiency is likely a result of an acidic surface treatment for bulk CdTe material that is intended to prepare the material for contacting but leaves a residual Te-rich layer on the surface that does not provide sufficient passivation for current charge carrier concentrations. New methods of preparing bulk CdTe material for contacting that reduce the portion of Te present on the surface of the device are necessary for further efficiency gains. 

Description

Researchers at NREL have invented a method of treating CdTe materials with a basic solution so that surface recombination is minimized. The treatment consistently leaves non-stoichiometric Cd-rich surfaces that can be reconstructed into a crystalline lattice that exhibits a significant increase in carrier lifetimes. The invention is valid over a range of temperatures and times that are suitable for industrial processing (5s – 5min, 20C – 65C) and has been demonstrated successfully in both air and inert environments. Devices created using this method increased near-surface charge carrier lifetimes enough that the true bulk lifetime of the material was observed.

Benefits
  • Increased device efficiency through decreased surface recombination
  • Easily implemented in industrial environments
  • Method works consistently at low cost
Applications and Industries
  • CdTe photovoltaics
Patents and Patent Applications
ID Number
Title and Abstract
Primary Lab
Date
Patent 9,722,111
Patent
9,722,111
Surface passivation for CdTe devices
In one embodiment, a method for surface passivation for CdTe devices is provided. The method includes adjusting a stoichiometry of a surface of a CdTe material layer such that the surface becomes at least one of stoichiometric or Cd-rich; and reconstructing a crystalline lattice at the surface of the CdTe material layer by annealing the adjusted surface.
National Renewable Energy Laboratory 08/01/2017
Issued
Technology Status
Technology IDDevelopment StageAvailabilityPublishedLast Updated
NREL ROI 14-39PrototypeAvailable09/07/201709/07/2017

Contact NREL About This Technology

To: Bill Hadley<bill.hadley@nrel.gov>