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Selective Hydrogen Monitoring Using Nanoparticle-based Functional Sensors

National Energy Technology Laboratory

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Technology Marketing Summary

Research is currently active on the patent pending technology titled, “Noble and Precious Metal Nanoparticle-Based Sensor Layers for Selective H2 Sensing.” This invention is available for licensing and/or further collaborative research from the U.S. Department of Energy’s National Energy Technology Laboratory.

Description

The ability to selectively sense hydrogen (H2) is important for a broad range of applications spanning energy, defense, aviation, and aerospace. One of the most significant needs is for sensors that are capable of H2 leak detection at levels up to the lower explosive limit (~4% in ambient air). Optical-based sensors offer distinct advantages for H2 sensing including broadband wavelength and distributed interrogation compatibility, resistance to electromagnetic interference, and the elimination of electrical wires and contacts, which are commonly associated with sensor failure and a potential safety concern for application in explosive gas atmospheres.

Palladium (Pd) and Pd-alloy thin films are the most common materials used for optical H2 sensing applications due to the dependence of the optical constants of Pd on ambient H2 concentration. This invention describes the development and use of thin film functional sensor layers integrated with optical based waveguide sensors for H2. The new sensor films consist of noble or precious metal nanoparticles such as Pd or Pd-alloys incorporated into a dielectric matrix to stabilize them while still providing access of H2 to the nanoparticles for operation as a functional sensor element. The companion film is a largely transparent (i.e., non-absorptive) dielectric material in the wavelength range of interest that exhibits high stability under harsh chemical and high temperature conditions with extremely limited diffusion of species other than hydrogen. The new nanocomposite systems described in this invention have been shown to have high sensitivity and selectivity for H2.

Pd nanoparticle-based H2 sensing layers have a number of potential advantages as compared to continuous thin films including response time, sensitivity, and stability of the microstructure at high temperatures or during H2 loading and unloading cycles as well as the ability to tune the optical constants of the sensing layer for optimal response in an optical sensing device platform.

Benefits
  • Sensors allows for selectively, optical, and remote monitoring of H2

  • Allows for distributed H2 sensing in an enclosed environment

  • Provides the ability to use advanced sensor design and interrogation techniques for performing hydrogen sensing

  • Eliminates the need for expensive conductive electrical wires with insulation capable of withstanding extreme temperatures and environments

  • Sensors have reduced interference, surface poisoning, and cross-gas sensitivity

Applications and Industries
  • Hydrogen sensing for process monitoring and/or control processes including dissolved hydrogen sensing in transformer oil, leak detection, metallurgical processes, solid oxide fuel cells, gas turbines, and other combustion environments

  • Aviation/aerospace and industrial manufacturing processes  

  • Monitoring of hydrogen in monolithic parts which have embedded optical fiber temperature sensors

More Information

U.S. Non Provisional Patent Application No. 14/887,660 filed October 20, 2015, titled “Palladium and Platinum-based Nanoparticle Functional Sensor Layers for Selective H2 Sensing.”

Inventors: Paul Ohodnicki Jr., John P. Baltrus, and Thomas Brown

U.S. Non Provisional Patent Application No. 15/641,193 filed July 3, 2017, titled "Palladium and Platinum-based Nanoparticle Functional Sensor Layers and Integration with Engineered Filter Layers for Selective H2 Sensing."

Inventors: Paul Ohodnicki Jr. John P. Baltrus, Thomas Brown, and Chenhu Sun

Patents and Patent Applications
ID Number
Title and Abstract
Primary Lab
Date
Patent 9,696,256
Patent
9,696,256
Palladium and platinum-based nanoparticle functional sensor layers for selective H2 sensing
The disclosure relates to a plasmon resonance-based method for H.sub.2 sensing in a gas stream utilizing a hydrogen sensing material. The hydrogen sensing material is comprises Pd-based or Pt-based nanoparticles having an average nanoparticle diameter of less than about 100 nanometers dispersed in an inert matrix having a bandgap greater than or equal to 5 eV, and an oxygen ion conductivity less than approximately 10.sup.-7 S/cm at a temperature of 700.degree. C. Exemplary inert matrix materials include SiO.sub.2, Al.sub.2O.sub.3, and Si.sub.3N.sub.4 as well as modifications to modify the effective refractive indices through combinations and/or doping of such materials. The hydrogen sensing material utilized in the method of this disclosure may be prepared using means known in the art for the production of nanoparticles dispersed within a supporting matrix including sol-gel based wet chemistry techniques, impregnation techniques, implantation techniques, sputtering techniques, and others.
U.S. Department of Energy 07/04/2017
Issued
Technology Status
Development StageAvailabilityPublishedLast Updated
PrototypeAvailable05/17/201705/17/2017

Contact NETL About This Technology

To: Jessica Sosenko<jessica.sosenko@netl.doe.gov>