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Overcharge Protection Prevents Exploding Lithium Ion Batteries

Lawrence Berkeley National Laboratory

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Technology Marketing Summary

Berkeley Lab scientists Guoying Chen and Thomas J. Richardson have invented a new type of separator membrane that prevents dangerous overcharge and overdischarge conditions in rechargeable lithium-ion batteries, i.e., exploding lithium ion batteries. This low cost separator, with electroactive polymers incorporated into a porous fiber membrane, provides electronic insulation and high ionic conduction during normal cell operation, enabling high charge and discharge rates for high power density.

Description

In overcharge and/or overdischarge situations, the membrane provides a reversible, self-actuated current shunt to prevent damage to the battery. By allowing other cells in the pack to continue charging, these separators balance the charge on each cell to extend battery life and use all of the available capacity. The threshold voltage for these membranes can also be tuned for different battery chemistries by using different electroactive polymers. Batteries incorporating such membranes thus have higher rate capability, improved safety, and longer cycle life.

When overcharged, lithium ion batteries may overheat, explode and cause fires. Even slight overcharging reduces a cell’s discharge capacity, leading to overdischarging, which increases impedance and heat generation, and decreases cell lifetime. Yet common approaches to preventing overcharge / overdischarge all have drawbacks. For example, external electronic controls add substantial weight, cost, and complexity to a battery pack. Shutdown separators that melt at ~160°C permanently disable the cell, increasing the strain on the remaining cells. Redox shuttle additives have limited sustainable current densities and cell charging rates, and do not work well at the low temperatures commonly experienced by vehicles. The Berkeley Lab overcharge protection technology overcomes limitations observed in other approaches to prevent overheating and exploding lithium ion batteries.

The LBNL-developed separator membrane provided long-term reversible overcharge protection for this lithium-ion cell, even after hundreds of continuous, full charge/discharge cycles over more than 1770 hours of operation.

The LBNL-developed separator membrane provided long-term reversible overcharge protection for this lithium-ion cell, even after hundreds of continuous, full charge/discharge cycles over more than 1770 hours of operation.

 

Benefits
  • Prevents overheating, exploding lithium ion batteries
  • Complete overcharge / overdischarge protection
  • Longer cycle life and battery life
  • Automatic cell balancing for maximum efficiency
  • Lower cost than electronic controls
  • Improved power density
Applications and Industries
  • Rechargeable lithium ion batteries for hybrid/electric automobiles
  • Consumer electronics
Patents and Patent Applications
ID Number
Title and Abstract
Primary Lab
Date
Application 20150125733
Application
20150125733
High-Rate Overcharge-Protection Separators for Rechargeable Lithium-Ion Batteries and the Method of Making the Same
This invention relates to low-cost, electroactive-polymer incorporated fine-fiber composite membranes for use as overcharge and/or overdischarge protection separators in non-aqueous electrochemical cells and the methods for making such membranes.
Lawrence Berkeley National Laboratory 05/14/2013
Filed
Technology Status
Technology IDDevelopment StageAvailabilityPublishedLast Updated
IB-3263ProposedAvailable01/26/201601/26/2016

Contact LBL About This Technology

To: Shanshan Li<ipo@lbl.gov>