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Fluorine-Modified Polyaromatic Hydrocarbons for Organic Electronics

Colorado State University

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Technology Marketing Summary

A chemical synthesis that modifies PAHs via addition of perfluoroalkyl groups. The resulting compounds are novel organic semiconductors with potential application to flexible OLED displays and organic photovoltaics (OPVs).
 

Description

The laboratory of Dr. Steven Strauss has been a pioneer in the field of fluorination and perfluoroalkylation chemistry for over a decade. They have become world experts in the fluorination of various forms of “nanocarbon”, in particular fullerenes (aka buckyballs) and more recently a class of compounds known as polycyclic aromatic hydrocarbons (PAHs). To be useful, PAHs must be chemically altered so as to optimize their electronic properties. Typically, these reactions are difficult to control, expensive, and result in highly impure products.
The Strauss group has developed a perfluoroalkylation synthesis technique that is easily controlled and is highly selective – thus it results in very pure products. The method is general and can be used to modify a wide variety of PAHs. The procedure is a one-step reaction that does not require a solvent (is thus a very “green” chemistry).
In addition to a novel synthesis technique, this technology has opened the door to a whole new class of compounds, most of which can be patented as novel compositions of matter. Excitingly, these modified PAHs behave as organic semiconductors with electronic properties that appear to be well-suited for the light absorbing component of organic photovoltaic.
Broadly, organic semiconductors represent a large emergent market segment that promises to bring a new revolution of flexible and cheap consumer electronics and conformal power generation devices (solar cells that can be easily mounted on curved surfaces, such as cars, buildings, and any large structures). Commercial devices based on organic light emitting diodes are already available (smartphones and large displays by Samsung and Sony and even head-mount displays by Zeiss).
This technology has clear application in the area of organic electronic devices, including highly energy efficient OLED technology and OPV. Organic electronics are attractive to industry for many reasons and may be especially vital to the emerging area of flexible electronics. OLED technology is already a global industry.

Benefits
  • Chemical synthesis that controllably adds perfluoroalkyl groups to nearly any polycyclic aromatic hydrocarbon (PAH).
  • Resulting compounds are novel organic semiconductors with advantageous and customizable electronic properties.
Applications and Industries

Application to flexible electronics such as OLED displays and organic photovoltaic solar cells (OPVs).

Patents and Patent Applications
ID Number
Title and Abstract
Primary Lab
Date
Application 20140221655
Application
20140221655
MODIFIED POLYAROMATIC HYDROCARBONS AND POLYHETEROCYCLICS FOR OPTOELECTRONICS
The invention provides methods for substituting polyaromatic hydrocarbons or polyheterocyclic compounds with perfluoroalkyl groups. The methods can include heating a polyaromatic hydrocarbon substrate or a polyheterocyclic compound substrate in the presence of a perfluoroalkyl iodide, typically in a closed system, wherein the heating is sufficient to bring both the polyaromatic hydrocarbons or polyheterocyclic compound, and the perfluoroalkyl iodide, into the gas phase, thereby allowing the substrate to react with the perfluoroalkyl iodide in the gas phase to form polyaromatic hydrocarbons or polyheterocyclic compounds having one or more perfluoroalkyl substituents. The methods allow for the creation of versatile libraries of novel perfluoroalkyl-containing derivatives that can serve as important building blocks and active components in biomedical, electronic, and materials applications.
02/06/2014
Filed
Technology Status
Technology IDDevelopment StageAvailabilityPublishedLast Updated
12-042PrototypeAvailable09/25/201409/25/2014

Contact CSU About This Technology

To: Jeremy Nelson<jeremy.nelson@colostate.edu>