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Accurate Detection of Impurities in Hydrogen Fuel at Lower Cost

Advancing the science of fuel cells for advanced technology vehicles

Argonne National Laboratory

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<p align="LEFT">
	<i><font color="#808285" size="1"><font color="#808285" size="1">Conceptual diagram of a hydrogen-permeating enrichment device. (simplified to protect information for potential licensees) </font></font></i></p>

Conceptual diagram of a hydrogen-permeating enrichment device. (simplified to protect information for potential licensees)

<p align="LEFT">
	<i><font color="#808285" size="1"><font color="#808285" size="1">Pressure-swing enrichment device. (simplified to protect information for potential licensees)</font></font></i></p>

Pressure-swing enrichment device. (simplified to protect information for potential licensees)

Technology Marketing Summary

Scientists at Argonne National Laboratory have developed two alternative strategies for detecting impurities in the hydrogen used in fuel cells. Both yield highly accurate results and use simpler, less costly equipment.

As the United States gradually establishes a refueling infrastructure for fuel cell vehicles, lawmakers will adopt standards for impurities in the hydrogen used in these vehicles. Impurities can cause fuel cell performance degradation and catalyst poisoning. Such standards require that hydrogen producers, vendors and regulators be able to detect impurities and certify that they are present only at very low concentrations. Currently, detecting such trace levels requires highly sensitive, costly equipment.

Description

In the first strategy, Argonne researchers took advantage of the high pressure of hydrogen at the dispenser nozzle. By removing the hydrogen through a special membrane, scientists can isolate the remaining impurities at a higher concentration. Once concentrated, the impurities are easily detected using less costly, potentially portable sensors (Figure 1).

Argonne’s second strategy uses an enrichment device that employs a pressure-swing adsorption cycle (Figure 2). In this device, the sample gas is passed through a bed of sorbents at high pressure so that the impurities are adsorbed on the sorbent surface. Releasing the pressure in the sorbent chamber then releases the impurities into the gas phase to elevate their concentrations in that space. The enrichment factor for each gas species depends on the sorbent and the gas species used in the pressure-swing enrichment device; it typically exceeds one order of magnitude.

Argonne’s concepts are novel and provide inexpensive solutions to a significant problem. Although other organizations are working on similar concepts, Argonne is the first to publish the results of research into this technology.

Benefits
  • Facilitates the analysis of trace impurities in high-pressure hydrogen streams
  • Replaces costly analytical equipment with inexpensive, easy-to-operate sensor devices that are potentially portable
  • Allows rapid, repeated analyses to assure quality
Applications and Industries
  • Analysis of hydrogen quality at distributed hydrogen refueling stations
  • Analysis of hydrogen quality at central hydrogen production plants, such as oil or chemical refining plants
  • Analysis of trace species in high-pressure hydrogen samples at refueling stations or in the laboratory
More Information

Ready for field testing at refueling stations where high-pressure hydrogen is available.

The devices can be specially tailored for potential users, including hydrogen producers, state regulators or vendors providing analytical services, and can be used to monitor single or multiple species for process quality assurance.

Patents and Patent Applications
ID Number
Title and Abstract
Primary Lab
Date
Patent 8,778,694
Patent
8,778,694
Batch methods for enriching trace impurities in hydrogen gas for their further analysis
Provided herein are batch methods and devices for enriching trace quantities of impurities in gaseous mixtures, such as hydrogen fuel. The methods and devices rely on concentrating impurities using hydrogen transport membranes wherein the time period for concentrating the sample is calculated on the basis of optimized membrane characteristics, comprising its thickness and permeance, with optimization of temperature, and wherein the enrichment of trace impurities is proportional to the pressure ratio P.sub.hi/P.sub.lo and the volume ratio V.sub.1/V.sub.2, with following detection of the impurities using commonly-available detection methods.
07/15/2014
Issued
Technology Status
Technology IDDevelopment StageAvailabilityPublishedLast Updated
IN-08-072PrototypeAvailable07/01/201307/01/2013

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To: Elizabeth Jordan<partners@anl.gov>