Skip to Content
Find More Like This
Return to Search

Zinc titanate sorbents

United States Patent

*** EXPIRED ***
February 3, 1998
View the Complete Patent at the US Patent & Trademark Office
The present invention provides a zinc titanate sorbent material useful in desulfurization applications. The zinc titanate material is in the form of generally spherical particles of substantially uniform chemical distribution. The sorbent material is capable of absorbing sulfur compounds from a gaseous feed in an amount of at least about 15 weight percent based on the weight of the sorbent. The sorbent material is prepared by a process including: (a) forming a zinc oxide/titanium dioxide dry blend, (b) preparing a substantially uniform aqueous slurry comprising the zinc oxide/titanium dioxide dry blend, organic binder, and at least about 1 weight percent inorganic binder based on the solids weight of the slurry, (c) spray drying the slurry to produce substantially spherical particles, and (d) calcining the particles at a temperature of between about C. to about C. The dry blend is formed by mixing between about 0.5 to about 2 parts zinc oxide having a median particle size of less than about 0.5 .mu., and about 1 part titanium dioxide having a median particle size of less than about 1 .mu.. The slurry contains substantially no free silica and may be prepared by the process including (1) preparing an aqueous solution of organic binder, (2) adding the dry blend to the aqueous solution of organic binder, and (3) adding the inorganic binder to the solution of organic binder, and blend. Additional reagents, such as a surfactant, may also be incorporated into the sorbent material. The present invention also provides a process for desulfurizing a gaseous stream. The process includes passing a gaseous stream through a reactor containing an attrition resistant zinc titanate sorbent material of the present invention.
Gupta; Raghubir P. (Durham, NC), Gangwal; Santosh K. (Durham, NC), Jain; Suresh C. (Germantown, MD)
Research Triangle Institute (Research Triangle Park, NC)
08/ 325,853
October 19, 1994
This invention was made with Government Support under Contract No. DE-AC21-88MC25006 awarded by the United States Department of Energy. The Government has certain rights in this invention.