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Halogenation of cobalt dicarbollide

United States Patent

*** EXPIRED ***
May 20, 1997
View the Complete Patent at the US Patent & Trademark Office
Los Alamos National Laboratory - Visit the Technology Transfer Division Website
A method for selectively adding chlorine, bromine, or iodine to cobalt dicarbollide anions by means of electrophilic substitution reactions. Halogens are added only to the B10 and B10' positions of the anion. The process involves use of hypohalous acid or N-halosuccinimide or gaseous chlorine in the presence of iron.
Hurlburt; Paul K. (Los Alamos, NM), Abney; Kent D. (Los Alamos, NM), Kinkead; Scott A. (Los Alamos, NM)
The Regents of the University of California (Alameda, CA)
08/ 455,372
May 31, 1995
BACKGROUND OF THE INVENTION This invention relates to the field of materials science and, more particularly, to nonmetallic materials and powder metallurgy. This invention was made with government support under Contract No. W-7405-ENG-36 awarded by the U.S. Department of Energy. The government has certain rights in the invention.