Skip to Content
Find More Like This
Return to Search

Palladium and platinum-based nanoparticle functional sensor layers for selective H2 sensing

United States Patent

July 4, 2017
View the Complete Patent at the US Patent & Trademark Office
U.S. Department of Energy - Visit the Office of the Assistant General Counsel for Technology Transfer & Intellectual Property Website
Selective Hydrogen Monitoring Using Nanoparticle-based Functional Sensors
The disclosure relates to a plasmon resonance-based method for H.sub.2 sensing in a gas stream utilizing a hydrogen sensing material. The hydrogen sensing material is comprises Pd-based or Pt-based nanoparticles having an average nanoparticle diameter of less than about 100 nanometers dispersed in an inert matrix having a bandgap greater than or equal to 5 eV, and an oxygen ion conductivity less than approximately 10.sup.-7 S/cm at a temperature of C. Exemplary inert matrix materials include SiO.sub.2, Al.sub.2O.sub.3, and Si.sub.3N.sub.4 as well as modifications to modify the effective refractive indices through combinations and/or doping of such materials. The hydrogen sensing material utilized in the method of this disclosure may be prepared using means known in the art for the production of nanoparticles dispersed within a supporting matrix including sol-gel based wet chemistry techniques, impregnation techniques, implantation techniques, sputtering techniques, and others.
Ohodnicki, Jr.; Paul R. (Alison Park, PA), Baltrus; John P. (Jefferson Hills, PA), Brown; Thomas D. (Finleyville, PA)
U.S. Department of Energy (Washington, DC)
14/ 887,660
October 20, 2015
GOVERNMENT INTERESTS The United States Government has rights in this invention pursuant to the employer-employee relationship of the Government to the inventors as U.S. Department of Energy employees and site-support contractors at the National Energy Technology Laboratory.