The present disclosure relates to multichromophoric assemblies comprising metalloporphyrin scaffolds. The present disclosure also relates, in part, to methods for generating electric-field-stabilized geminate polaron pairs comprising applying electric fields to the multichromophoric assemblies described herein, or alternatively, directly to the metalloporphyrins provided by the present disclosure. The present disclosure further relates, in part, to multichromophoric assemblies comprising metalloporphyrin scaffolds, which exhibit enhanced energy transfer properties.
STATEMENT REGARDING FEDERALLY SPONSORED RESEARCH
The subject matter of this application was prepared with U.S. Government support under Grant No. DE-SC0001011 awarded by the Department of Energy. The government has certain rights in the subject matter of this application.