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Semi-solid electrodes having high rate capability

United States Patent

June 7, 2016
View the Complete Patent at the US Patent & Trademark Office
Embodiments described herein relate generally to electrochemical cells having high rate capability, and more particularly to devices, systems and methods of producing high capacity and high rate capability batteries having relatively thick semi-solid electrodes. In some embodiments, an electrochemical cell includes an anode and a semi-solid cathode. The semi-solid cathode includes a suspension of an active material of about 35% to about 75% by volume of an active material and about 0.5% to about 8% by volume of a conductive material in a non-aqueous liquid electrolyte. An ion-permeable membrane is disposed between the anode and the semi-solid cathode. The semi-solid cathode has a thickness of about 250 .mu.m to about 2,000 .mu.m, and the electrochemical cell has an area specific capacity of at least about 7 mAh/cm.sup.2 at a C-rate of C/4. In some embodiments, the semi-solid cathode slurry has a mixing index of at least about 0.9.
Chiang; Yet-Ming (Weston, MA), Duduta; Mihai (Somerville, MA), Holman; Richard (Wellesley, MA), Limthongkul; Pimpa (Boston, MA), Tan; Taison (Cambridge, MA)
24M Technologies, Inc. (Cambridge, MA)
14/ 719,566
May 22, 2015
STATEMENT REGARDING FEDERALLY SPONSORED RESEARCH OR DEVELOPMENT This invention was made with government support under Grant Number DE-AR0000102 awarded by the Department of Energy. The government has certain rights in the invention.