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Color stable phosphors for LED lamps and methods for preparing them

United States Patent

November 26, 2013
View the Complete Patent at the US Patent & Trademark Office
An LED lamp includes a light source configured to emit radiation with a peak intensity at a wavelength between about 250 nm and about 550 nm; and a phosphor composition configured to be radiationally coupled to the light source. The phosphor composition includes particles of a phosphor of formula I, said particles having a coating composition disposed on surfaces thereof; ((Sr.sub.1-zM.sub.z).sub.1-(x+w)A.sub.wCe.sub.x).sub.3(Al.sub.1-ySi.sub.y- )O.sub.4+y+3(x-w)F.sub.1-y-3(x-w) I wherein the coating composition comprises a material selected from aluminum oxide, magnesium oxide, calcium oxide, barium oxide, strontium oxide, zinc oxide, aluminum hydroxide, magnesium hydroxide, calcium hydroxide, barium hydroxide, strontium hydroxide, zinc hydroxide, aluminum phosphate, magnesium phosphate, calcium phosphate, barium phosphate, strontium phosphate, and combinations thereof; and A is Li, Na, K, or Rb, or a combination thereof; M is Ca, Ba, Mg, Zn, or a combination thereof; and 0<x.ltoreq.0.10, 0.ltoreq.y.ltoreq.0.5, 0.ltoreq.z.ltoreq.0.5, 0.ltoreq.x.ltoreq.x.
Murphy; James Edward (Niskayuna, NY), Setlur; Anant Achyut (Niskayuna, NY), Camardello; Samuel Joseph (Albany, NY)
General Electric Company (Niskayuna, NY)
13/ 080,099
April 5, 2011
STATEMENT REGARDING FEDERALLY SPONSORED RESEARCH AND DEVELOPMENT This invention was made with Government support under contract number DE-FC26-06NT42934 awarded by the U.S. Department of Energy. The Government has certain rights in the invention.