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Calibration-free optical chemical sensors

United States Patent

April 11, 2006
View the Complete Patent at the US Patent & Trademark Office
An apparatus and method for taking absorbance-based chemical measurements are described. In a specific embodiment, an indicator-based pCO.sub.2 (partial pressure of CO.sub.2) sensor displays sensor-to-sensor reproducibility and measurement stability. These qualities are achieved by: 1) renewing the sensing solution, 2) allowing the sensing solution to reach equilibrium with the analyte, and 3) calculating the response from a ratio of the indicator solution absorbances which are determined relative to a blank solution. Careful solution preparation, wavelength calibration, and stray light rejection also contribute to this calibration-free system. Three pCO.sub.2 sensors were calibrated and each had response curves which were essentially identical within the uncertainty of the calibration. Long-term laboratory and field studies showed the response had no drift over extended periods (months). The theoretical response, determined from thermodynamic characterization of the indicator solution, also predicted the observed calibration-free performance.
DeGrandpre; Michael D. (Missoula, MT)
The University of Montana (Missoula, MT)
09/ 775,386
January 31, 2001
The subject invention was made with government support under a research project supported by the Department of Energy Ocean Margins Program Grant No. DOE-DEFG03-94ER6224. The government has certain rights in this invention.