Skip to Content
Find More Like This
Return to Search

Materials and methods for the separation of oxygen from air

United States Patent

July 15, 2003
View the Complete Patent at the US Patent & Trademark Office
Metal oxides particularly useful for the manufacture of catalytic membranes for gas-phase oxygen separation processes having the formula: where: x and x' are greater than 0; y and y' are greater than 0; x+x' is equal to 2; y+y' is less than or equal to 2; z is a number that makes the metal oxide charge neutral; A is an element selected from the lanthanide elements; A' is an element selected from Be, Mg, Ca, Sr, Ba and Ra; A" is an element selected from the f block lanthanides, Be, Mg, Ca, Sr, Ba and Ra; B is an element selected from the group consisting of Al, Ga, In or mixtures thereof and B" is Co or Mg, with the exception that when B" is Mg, A' and A" are not Mg. The metal oxides are useful for preparation of dense membranes which may be formed from dense thin films of the mixed metal oxide on a porous metal oxide element. The invention also provides methods and catalytic reactors for oxygen separation and oxygen enrichment of oxygen deficient gases which employ mixed conducting metal oxides of the above formula.
MacKay; Richard (Lafayette, CO), Schwartz; Michael (Boulder, CO), Sammells; Anthony F. (Boulder, CO)
Eltron Research, Inc. (Boulder, CO)
09/ 748,344
December 22, 2000
STATEMENT OF GOVERNMENT SUPPORT The research for this invention was supported by a grant from the U.S. Department of Energy, Grant No. DE-FG03-96ER82215. The United States government may have certain rights in this invention.