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Sulfur-Graphene Oxide Nanocomposite Cathodes for Lithium/Sulfur Cells
A Berkeley Lab team headed by Yuegang Zhang and Elton Cairns has developed a method to fabricate battery cathodes from nanoscale flakes of graphene oxide and sulfur. This innovation solves at once two design problems that have impeded efforts to make commercially viable lithium-sulfur (Li-S) batteries: 1) sulfur is a natural insulator, and designers must find ways to overcome its resistance; 2) Li-S batteries are notoriously short-lived because sulfur that dissolves in the electrolyte can...
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| 04/30/2013 New! |
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Organic Flash Cycles for Intermediate and High Temperature Waste Reclamation
Researchers at Berkeley Lab have developed a highly efficient technology for the reclamation of waste heat in mechanical heat engines widely used in solar-thermal, geothermal, and industrial processes. This new approach yields gains in efficiencies for both high temperature and intermediate temperature thermal sources, marking a significant advance over strategies that focus predominately on high temperature efficiency solutions.
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| 04/30/2013 New! |
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Hydrogen-Evolving Organic Compounds
A system, that includes a catalyst and organic compound, for storing and releasing hydrogen at or near ambient temperature. |
| 04/04/2013 Updated! |
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Hybrid System for Separating Oxygen from Air
Sandia has developed a portable, oxygen generation system capable of delivering oxygen gas at purities greater than 98 percent and flow rates significantly greater than commercially available systems. |
| 03/12/2013 |
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Non-Invasive Energy Meter
Sandia has developed an energy monitoring device that measures energy from liquid flow systems (e.g., solar systems) using a simple technique that senses when the system is running and then estimates the BTU energy production. Current energy meters must be installed into the system to measure how much energy the system is producing or losing. This involves cutting pipes, installing thermal wells, and flow meters, and/or connecting sensors to pump motors in the system. This often requires...
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| 03/12/2013 |
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Molten Salt Heat Transfer Fluid (HTF)
Sandia has developed a heat transfer fluid (HTF) for use at elevated temperatures that has a lower freezing point than any molten salt mixture available commercially. This allows the HTF to be used in applications in which the expensive parasitic energy costs necessary for freeze protection can be significantly reduced. The higher operating temperature limit significantly increases power cycle efficiency and overall power plan sun-to-net electric efficiency. |
| 03/12/2013 |
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Electrical Cable Testing by Pulse-Arrested Spark Discharge (PASD)
Sandia has developed an advanced electrical wiring diagnostic system capable of detecting insulation defects in complex wiring systems. The portable diagnostic system detects and accurately locates hard to find insulation defects as breached insulation, chaffing, and insulation cracks. PASD could greatly reduce the time required to track down wiring defects, as it can typically locate these defects within inches. |
| 03/12/2013 |
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Energy Surety Microgrid™
The Energy Surety Microgrid™ (ESM) is a Risk Assessment Methodology (RAM) which is a vulnerability assessment for the critical power delivery functions and needs of a community. The microgrid serves as a predecessor to the larger-scale smart grid making it more specific to serve hospitals, military bases, residential communities, emergency response, etc. in utilizing renewable energy sources when traditional sources fail or are inadequate. |
| 03/12/2013 |
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TOPHAT™ for the Alignment & Focus of Heliostat Mirror Facets
The Theoretical Overlay Photographic Heliostat Alignment Technique (TOPHAT) is a unique method which helps to accurately and effectively concentrate solar energy onto a receiver. By utilizing a camera/target fixture placed in front of the heliostat TOPHAT aligns and focuses the mirrors on a heliostat. It uses the photographs taken by cameras on the fixture and comparing the location and size of the target patterns with their predicted theoretical images. Adjustments are made to the facets until...
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| 03/12/2013 |
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“Smart” Frequency-Sensing Charge Controller for Electric Vehicles
As plug-in hybrid electric vehicles (PHEVs) and battery electric vehicles (BEVs) become more popular, they create additional demand for electricity. Their emergence also raises a host of issues regarding how, where and when car batteries should be charged—and the resulting load on the power grid.
Electric utilities strive to avoid large fluctuations in the power supply and to keep the system’s frequency stable at 60 Hz. In this way, they maintain balance in supply and demand and...
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| 02/28/2013 |
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Autogenic pressure reactors provide simple, rapid means of producing battery materials
Rechargeable lithium-ion batteries have become the battery of choice for everything from cell phones to electric cars, but there is still much room for improvement. Scientists at Argonne National Laboratory are leading efforts to revolutionize battery technology with the design and development of new battery materials for electrolytes, electrodes, and interfaces that will increase the specific energy of advanced batteries, while simultaneously providing enhanced stability at a lower cost. To...
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| 02/28/2013 |
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Frequency Stabilization in Non-linear MEMS and NEMS Oscillators (IN-11-087)
Mechanical oscillators are an important component in electronic devices and they represent a multi-billion dollar industry. As electronics become increasingly miniaturized, oscillators must become smaller as well and this makes them more sensitive to environmental variations. Scientists at Argonne National Laboratory have devised a method to solve this problem that allows creating micro and nano mechanical oscillators with excellent frequency stability. |
| 02/25/2013 |
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Cathode Coating (IN-09-061)
A team of scientists at Argonne National Laboratory has developed a special coating for the cathodes used in lithium batteries. With the coating, batteries charge and discharge more quickly, without a loss in performance. |
| 02/25/2013 |
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Lithium Iron Phosphate Composites for Lithium Batteries (IN-11-024)
Argonne National Laboratory has developed a series of inexpensive, electrochemically active phosphate compounds that are highly functional when used in high-power and high-energy lithium batteries. |
| 02/25/2013 |
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Nanosegregated Surfaces as Catalysts for Fuel Cells (IN-07-054)
Fuel cells are an important component in the energy industry, but the high cost of producing the platinum catalyst—an essential part of a fuel cell—has historically kept fuel cells from being commercially viable. Scientists at Argonne National Laboratory have devised a process for creating a “nanosegregated” platinum alloy catalyst with significantly enhanced properties, making it cost-effective and highly attractive for use in fuel cells. |
| 02/11/2013 |
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Nanotube Arrays for Advanced Lithium-ion Batteries
The development of high-power, high-energy, long-life, and low-cost rechargeable batteries is critical for the next-generation electric and hybrid electric vehicles. Among various battery technologies, lithium-ion batteries (LIBs) are promising energy storage devices as a result of the high energy densities, low self-discharges, and long cycle lives of known LIBs. Market analysis projects that the LIB market will increase to over $77 billion within the energy storage, electric vehicles, and...
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| 01/31/2013 |
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Negative Electrodes Improve Safety in Lithium Cells and Batteries
To help improve the stability and safety of lithium-ion batteries, Argonne researchers have developed a new intermetallic structure type that can be used for the battery’s negative electrode. Rechargeable lithium-ion batteries have become the battery of choice for everything from cell phones to electric cars, but there is still much room for improvement. Scientists at Argonne National Laboratory are leading efforts to revolutionize battery technology with the design and development of new...
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| 01/18/2013 |
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Methodology for producing internal short for safety in energy storage devices
Energy storage cells (also referred to herein as "cells" or "batteries") sold for consumer use in portable electronic devices and other applications have occasional failure in the field. These cells have typically passed a wide variety of safety tests, such as those required by governmental shipping regulations and by other certification organizations, but fail after the cells have been in use over time (e.g., several months), even though there have been no other reported problems with the...
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| 01/08/2013 |
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Synthesis of Ionic Liquids
Chemical separation, such as processes producing alkanes from olefins, often requires series of distillation steps that are highly energy intensive.
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| 09/22/2012 |
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Battery – Sensor Monitor
INL researchers have invented a method to evaluate materials using an impedance method, rather than relying upon nondestructive techniques optical, acoustic, radiographic and electromagnetic techniques. |
| 09/04/2012 |
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Superhydrophobic Coating for Evaporative Purification and Minerals Extraction
Researchers at ORNL are using their superhydrophobic coating technology to tackle the age-old problem of obtaining potable water. In the process, they have also developed a cost-effective method to extract industrial minerals and metals such as potassium, lithium, and magnesium from the seas and other waters. Potable water is becoming an increasingly scarce resource. Evaporative desalination is one of the cheapest, easiest, simplest ways to covert salt or brackish water into fresh water....
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| 08/21/2012 |
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Pulsed Ionization Source for Ion Mobility Spectrometers
ORNL’s new wave of detection devices based on ion mobility spectrometry offer enhanced sensitivity and resolution and increased safety and flexibility. Leading the way is a miniature ion mobility spectrometer (IMS) that uses a pulsed corona ionization source. This detector has demonstrated both high sensitivity and high resolution without the drawbacks of other systems.
Ion mobility spectrometry is an important method for detecting drugs, explosives, volatile organic compounds, and chemical...
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| 08/21/2012 |
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Synthesis Method for Stable Colloids of "Naked" Metal Nanocrystals
Researchers at ORNL have developed a unique membrane-assisted thermal electrochemical synthesis (TECS) process for making colloidally stable aqueous solutions of small (<10 nm) metallic nanocrystals that are "clean," stable, and uniform in size. The nanocrystals produced by the TECS process represent a unique class of colloids that could be used in a variety of applications, including coatings, catalysts, and sensor devices.
Metallic nanocrystals have generated considerable interest because...
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| 07/11/2012 |
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Organic-Inorganic Complexes Containing a Luminescent Rare Earth-Metal Nanocluster and an Antenna Ligand, Luminescent Articles, and Methods of Making Luminescent Articles
Battelle has developed a material capable of spectral conversion, that is, absorbing light across a broad range of wavelengths and re-emitting this light in a narrow wavelength range. These materials can then be integrated into devices to convert solar radiation into energy. In one implementation, this material can be applied to a solar cell to enhance the absorption efficiency of the solar cell. In a second implementation, this material can be placed between two panes of glass, and used to...
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| 06/11/2012 |
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Supercapacitor Materials and Devices: Nickel-Cobalt Supercapacitors and Methods of Making Same
Battelle has developed materials that can be used to create a supercapacitor with performance superior to that of commercially available devices. The common measures of performance are the energy density (energy per kg) and power density (power per kg). This technology is based on specific metal oxide compositions synthesized in conjunction with carbon nanotubes or activated carbon. The performance of the supercapacitor can be tuned by altering the specific metal oxide...
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| 06/11/2012 |
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Lithium Salt-doped, Gelled Polymer Electrolyte with a Nanoporous, Bicontinuous Cubic Architecture and High Room-temparature Ion Conductivity
Li ion batteries have high energy density, high power delivery, and the ability to be recharged over a large number of cycles. One component that needs to be improved to make them suitable for high performance applications is the electrolyte material . High Li ion mobility/conductivity in electrolyte material is required for larger energy applications, and efficient discharge and recharge with a minimum of power loss to resistive heating. However, these electrolytes can leak from the battery,...
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| 06/01/2012 |
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Nanostructured, Rechargeable Solid-State Composite Batteries
Research on all-solid-state rechargeable lithium batteries has increased considerably in recent years due to raised concerns relating to safety hazards such as solvent leakage and flammability of liquid electrolytes used for commercial lithium-ion batteries. As solid state electrolytes by nature do not carry the safety burdens of liquid electrolytes, an extensive worldwide effort is under way to produce a viable substitute solid electrolyte to replace conventional liquid electrolytes....
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| 06/01/2012 |
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Solid-state Inorganic Lithium-Ion Conductors
A research team at the University of Colorado Boulder led by Se-Hee Lee has developed an advanced single step, high energy ball milling system for preparation of electrodes for use in a solid state lithium-ion battery.
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| 05/23/2012 |
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Fail-Safe Design for Large Capacity Li-Ion Battery Systems
Lithium-ion batteries (LIBs) are a promising candidate for energy storage of electric drive vehicles due to their high power and energy density. The total electric vehicle LIB market shipped 2,400 units in 2008 generating over $28 million in revenue and is predicted to be greater than $10 billion by 2015. However, violent incidents reported for LIBs and consequent safety concerns pose a major obstacle to LIB market acceptance. Safety mitigation technologies used in small capacity consumer...
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| 04/25/2012 |
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Low-temperature Sodium-Beta Battery
Rechargeable metallic sodium batteries have application in large-scale energy storage applications such as electric power generation and distribution, in motive applications such as electric vehicles, hybrids, and plug-in hybrids, and for aerospace applications such as powering satellites. So far, two sodium-based battery technologies have shown particular commercial promise: sodium-sulfur and sodium-nickel chloride, both referred to as sodium-beta batteries. Sodium-β battery...
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| 04/04/2012 |
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Advanced Solid State Li-Ion Battery
Research on all-solid-state rechargeable lithium batteries has increased considerably in recent years due to raised concerns relating to safety hazards such as solvent leakage and flammability of liquid electrolytes used for commercial lithium-ion batteries. As solid state electrolytes do not carry the safety burdens of liquid electrolytes and are more effective, an effort is under way to produce a viable substitute solid electrolyte to replace conventional liquid electrolytes. Yet another...
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| 03/28/2012 |
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Polyanionic Polymers with High Alkali-Ion Conductivity and Wide Electrochemical Windows
As mobile electronics continue to evolve, the need for high-output, long-lasting rechargeable batteries has grown tremendously. In the search for suitable materials from which to construct high energy density solid state batteries, one of the principal obstacles has been the provision of a suitable electrolyte that exhibits the right combination of conductivity and ion mobility, consistency, wide electrochemical window, and good adherence to electrode surfaces. Very few electrolytes have been...
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| 03/13/2012 |
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Environmentally Benign Electrolytes With Wide Electrochemical Windows
As mobile electronics continue to evolve, the need for safe, long-lasting rechargeable batteries has grown tremendously. In the search for suitable materials from which to construct high energy density solid state batteries, one of the principal obstacles has been the provision of a suitable electrolyte that exhibits the right combination of conductivity and ion mobility, consistency, wide electrochemical window, and good adherence to electrode surfaces. Very few electrolytes have been...
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| 03/13/2012 |
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Wide Electrochemical Window Solvents
Typical electrolyte solvents for use in liquid or polymer electrolyte solutions include alkyl ethers and alkene carbonates. These solvents are used to dissolve electrolyte solutes and/or rubberizing polymer additives to form electrolyte solutions which may be used in electrochemical devices. However, these materials have significant disadvantages. Ethers are volatile and have low dielectric constants, while carbonates are unstable around alkali metals and have high melting points. |
| 03/13/2012 |
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Lithium Ion Conducting Ionic Electrolytes
As mobile electronics continue to evolve, the need for high-output, long-lasting rechargeable batteries has grown tremendously. In the search for suitable materials from which to construct high energy density batteries, one of the principal obstacles has been the provision of a suitable electrolyte that exhibits the right combination of conductivity and ion mobility, stability, and wide electrochemical window. Very few electrolytes have been developed thus far that exhibit the above combination...
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| 03/13/2012 |
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Electrolytes for Lithium Ion Batteries
As mobile electronics continue to evolve, the need for high-output, long-lasting rechargeable batteries has grown tremendously. In the search for suitable materials from which to construct high energy density batteries, one of the principal obstacles has been the provision of a suitable electrolyte that exhibits the right combination of conductivity and ion mobility, stability, and wide electrochemical window. Very few electrolytes have been developed thus far that exhibit the above combination...
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| 03/13/2012 |
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Nanotube composite anode materials improve lithium-ion battery performance (ANL-09-034)
Rechargeable lithium-ion batteries are a critical technology for many applications, including consumer electronics and electric vehicles. As the demand for hybrid and electric vehicles continues to grow, so does the demand for lithium-ion batteries that are safer, more powerful, and less expensive. Scientists at Argonne National Laboratory are leading efforts to revolutionize battery technology with the design and development of new battery materials for electrodes, electrolytes, and interfaces...
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| 02/07/2012 |
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Electrode Materials for Rechargeable Li-ion Batteries: a New Synthetic Approach (ANL-IN-10-031)
Since the performance of Li-ion batteries is largely predicated on the cathode performance in the cell, improvements to lower the irreversibility capacity loss on the first cycle, increase the rate capability, and improve structural stability at high voltages in the cathode are needed. The objective is to synthesize and make new materials to address these issues. High-energy density Li-ion batteries available in the market today have low power and progressively lose their energy due...
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| 02/07/2012 |
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Advanced Carbon Aerogels for Energy Applications
Nanomaterials that are emerging out of cutting edge nanotechnology research are a key component for an energy revolution. Carbon-based nanomaterials are ushering in the “new carbon age” with carbon nanotubes, nanoporous carbons, and graphene nanosheets that will prove necessary to provide sustainable energy applications that lessen our dependence on fossil fuels.
Carbon aerogels (CAs) are nanoporous carbons that comprise a particularly significant class of carbon nanomaterials for...
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| 02/06/2012 |
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High-Voltage Insulators and Components
One of the ongoing challenges to improving performance in capacitors and other high-voltage electrical structures is to identify and reduce the factors that cause failure. High-voltage devices typically fail following excessive partial discharge activity, which is a localized dielectric breakdown that does not transcend the main electrode gap spacing. One type of failure is anticipated to start at a triple junction, the point at which an electrode and two different dielectric materials...
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| 02/06/2012 |
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Multilayer Graphene-Silicon Structures for Lithium Ion Battery Anodes
A team of Berkeley Lab researchers led by Yuegang Zhang and Liwen Ji has taken a major step toward an improved lithium ion battery with the development of anodes coated with vanishingly thin, alternating layers of graphene and silicon. Tests have shown that Berkeley Lab’s graphene-silicon layers create anodes with a much higher charge capacity than those made of graphite. In addition, the multilayer nanostructure of this easy-to-fabricate design resists the rapid degradation that...
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| 01/21/2012 |
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Lower Cost, Nanoporous Block Copolymer Battery Separator
Although the polyolefin polymer material often used for lithium battery separators costs approximately $1.30/kg, the difficult process used to make it porous, to allow the flow of ions and electrons, raises its cost by two-orders of magnitude, to $120–$240/kg. A Berkeley Lab team led by Nitash Balsara has developed an inexpensive and easily controlled process yielding a nanoporous polymer separator that performs just as well as those made by conventional means. |
| 01/21/2012 |
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Block Copolymer Cathode Binder to Simultaneously Transport Electronic Charge and Ions
A Berkeley Lab team led by Nitash Balsara has developed a highly efficient lithium ion battery in which a single inactive material—a polymeric binding agent—serves as a binder that holds active cathode materials together and as a two-lane conductor that simultaneously carries lithium ions and electronic charge. |
| 01/21/2012 |
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Neutron Detection Using an Embedded Sol-Gel Neutron Absorber
ORNL researchers invented a method for neutron detection that can play an important role in international safeguards and U.S. security. The technology, based on sol-gel chemistry, uses metallic oxides embedded in a glass film that fission when bombarded with neutrons, producing a signature event in the film. Using ultraviolet light, fission products of the metallic oxides and electron emissions can be quickly detected. |
| 10/27/2011 |
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Integrated Used Nuclear Fuel Storage, Transportation, and Disposal Canister System
Researchers at ORNL have developed an integrated system that reduces the total life-cycle cost of used fuel storage while improving overall safety. This multicanister approach provides superior assembly and burnup/damaged fuel capacity. The invention also reduces the need for future repackaging of fuel for transit or storage.
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| 10/25/2011 |
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Lithium/Sulfur Batteries Based on Doped Mesoporous Carbon
A sulfur/carbon composite material was prepared by heat treatment of doped mesoporous carbon and elemental sulfur at a temperature inside a stainless steel vessel, which was used in lithium/sulfur batteries that were tested in electrolytes. |
| 10/25/2011 |
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Rapid Gas Hydrate Formation Process
The Department of Energy’s National Energy Technology Laboratory (NETL) is seeking collaborative research and licensing partners interested in implementing United States Non-provisional Patent Application entitled “Rapid Gas Hydrate Formation Process.” Disclosed in this application is a method and device for producing gas hydrates from a two-phase mixture of water and a hydrate forming gas such as methane (CH4) or carbon dioxide (CO2). The two-phase mixture is created in a mixing zone, which...
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| 10/10/2011 |
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Acidic Ion Exchange Membrane
In this invention we report the synthesis of a copolymer of vinyl phosphonic acid (VPA) and vinyl zirconium phosphorous (VZP) acid has been achieved for the production of ion exchange membranes.
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| 10/06/2011 |
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Fiber-Optic Environmental Radiation Dosimeter
All-optical, fiber-optic-coupled remote radiation sensor using NRL’s luminescent, copper-doped quartz material. The key to the technology is the doped quartz material that produces a luminescence signal that is directly proportional to the radiation dose. Individual sensors have an estimated cost of $50 and a lifespan of decades. The sensor is less than 7 mm in diameter by 10 cm in length and is fiber-optic-coupled to a photodetec-tor that is remotely located away from the...
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| 10/06/2011 |
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Using Ionic Liquids to Make Titanium Dioxide Nanotubes
Since self-organized TiO2 nanotube (NT) arrays were first reported in 1999, there has been increasing research interest due to their comparably larger surface area, chemical stability, biocompatibility and the ability to provide an excellent electron percolation pathway for vectoral charge transfer between interfaces. The most commonly used fabrication method is anodization of titanium metal in aqueous or organic polarized electrolytes baths containing fluoride species such as NH4F, HF, or NaF....
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| 10/04/2011 |
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Mapping Battery Activity at the Level of a Billionth of a Meter
An ORNL method and apparatus offer a new approach to revealing battery behavior at the nanoscale. With this invention, researchers successfully mapped lithium diffusivity and electrochemical activity, showing how the battery works at the level of a billionth of a meter.
Future energy technologies will rely heavily on lithium-based batteries for electrochemical energy storage. To develop and to optimize battery performance, researchers need to understand how lithium, electron transport, and...
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| 10/04/2011 |
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Carbon Films Produced from Ionic Liquid Precursors
Researchers at ORNL have invented a more effective method of preparing thin carbons films, a material that has become increasing important to the development of energy-saving storage batteries. Using this new method, it is possible to produce a very resilient, thermally stable porous carbon film characterized by a highly ordered arrangement of uniformly sized pores.
Conventional polymer carbon precursors are typically in solid form and must first be dissolved in a solvent. This is a...
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| 10/04/2011 |
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“Brick-and-Mortar” Self-Assembly Approach to Mesoporous Carbon Nanocomposites
Mesoporous carbon materials lack sufficient ordering at the atomic scale to exhibit good conductivity properties and thermal stability. To date, mesoporous carbons having uniform mesopores and high surface areas have been prepared from partially graphitizable precursors in the presence of templates. High-temperature thermal treatments above 2000 C, which are usually required to increase conductivity, result in a partial or total collapse of the mesoporous structures and reduced surface areas...
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| 10/04/2011 |
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Real Space Mapping of Oxygen Vacancy Diffusion and Electrochemical Transformations by Hysteretic Current Reversal Curve Measurements
Electrochemical energy storage and conversion systems based on solid–gas and solid–liquid reactions and local bias-induced transformations are a vital component of future energy and information technologies. Development of high- energy and power-density materials necessitates understanding the nanoscale mechanisms involved in secondary batteries, fuel cell and air-battery operation. These mechanisms include the interplay between interfacial electrochemical reactions, oxygen vacancy...
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| 10/04/2011 |
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Redox Flow Batteries for Grid-scale Energy Storage
Though considered a promising large-scale energy storage device, the real-world deployment of redox flow batteries has been limited by their inability to work well in a wide range of temperatures and their relatively high cost. Historically, the state-of-the-art has been an all-vanadium redox flow battery using a sulfate-based electrolyte.
Researchers at PNNL have developed two novel approaches to redox flow batteries that overcome these barriers and offer superior performance and cost...
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| 10/03/2011 |
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Flywheel Energy Storage Device for Hybrid and Electric Vehicles
This cost-effective technology stores and reuses what would otherwise be wasted energy inside a hybrid electric vehicle engine. The invention, a mechanical flywheel coupled to a rotor inside the engine, stores rotational energy during engine performance, subsequently feeding it back to assist with acceleration and braking.
The device significantly improves fuel efficiency and does not conflict with other energy storage components, such as batteries. No special container is required, as the...
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| 09/29/2011 |
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Method of Production of Pure Hydrogen Near Room Temperature From Ultra High Capacity Hydride Materials
This is a cost-effective method for the production of pure hydrogen gas from ultra high capacity hydride solid materials. |
| 09/22/2011 |
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Redox Shuttle Electrolyte Additive Could Help Make Batteries Safer, More Economical
Argonne National Laboratory has developed a way to make commercially viable lithium-ion (Li-ion) batteries for plug-in hybrid electric vehicles (PHEVs) and electric vehicles that are safer, will last longer, and cost less than current Li-ion batteries. Argonne researchers, Drs. Khalil Amine and Zonghai Chen, accomplished this goal by making only a small change to the Li-ion chemistry. The scientists are testing a new molecule based on boron and fluorine as an additive in the electrolyte of...
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| 09/16/2011 |
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Environmental Energy Harvesting
Energy harvesting is a developing technology that seeks to exploit naturally-occurring energy to power systems, rather than relying on external sources such as batteries. Lawrence Livermore National Laboratory has developed a method and a device for capturing the chemical energy in organic molecules and converting it into electrical energy. Vibration-based conversion has been commercialized to piezoelectric devices, and the LLNL team believes the time right for matrix-assisted energy...
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| 07/27/2011 |
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Advanced Lithium Ion Battery Technologies
Scientists at Berkeley Lab have invented highly conductive polymer binder materials that significantly improve the viability of using silicon as an electrode material in lithium ion batteries. They have also combined lithium metal with the Berkeley Lab conductive binder, plus other materials, to create a hybrid electrode system for use in lithium ion batteries.
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| 07/26/2011 |
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High Capacity Hydrogen Storage Nanocomposite
Scientists at the Savannah River National Laboratory's (SRNL) Hydrogen Research Center have developed new processes to add metal hydrides to nanocarbon structures to yield high capacity hydrogen storage materials. Testing of these materials has shown that hyrdogen can be efficiently absorbed and released in multiple cycles and in significant quantities. Processes to add Lithium Hydride to Fullerenes have resulted in structures that can retain and release significant quantities of...
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| 06/21/2011 |
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High-performance Electrochemical Capacitors
A capacitor comprising an anode, cathode, and an electrolyte, wherein the anode, the cathode, or both comprise a composite of porous carbon structure with a coating on the surface of MnO2, and a current collector in electrical contact with the composite |
| 05/23/2011 |
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Ruthenium on Carbon Nanostructures for Supercapacitor Electrodes
Supercapacitors are electrical storage devices that can deliver a huge amount of energy in a short time. Such a surge of energy is important in hybrid electric and fuel cell-powered vehicles, as well as in a wide range of electronic and engineering applications. Since the energy storage capability and the current carrying capability of supercapacitors are proportional to their capacitance, it is important to have as much surface area as possiblein the electrode. A smooth and conformal adlayer...
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| 04/29/2011 |
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Hydrogen and Elemental Carbon Production from Natural Gas and Other Hydrocarbons
INL has developed a fast quench reactor process to produce diatomic hydrogen and unsaturated hydrocarbons. During the fast quench, the unsaturated hydrocarbons are further decomposed by reheating the reactor gases. More diatomic hydrogen is produced, along with elemental carbon. Other gas may be added at different stages in the process to form a desired end product and prevent back reactions. The product is a substantially clean-burning hydrogen fuel that leaves no greenhouse gas emissions and...
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| 04/27/2011 |
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Metal-Air Battery
This technology features cathodes for use in open electrochemical cells and devices comprising the cathodes and open electrochemical cells. |
| 04/27/2011 |
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MEMS Fuel Cells--Low Temp--High Power Density
Rechargeable batteries presently provide limited energy density and cyclical lifetime for portable power applications, with only incremental improvements forecasted in the foreseeable future. Furthermore, recharging requires access to electrical outlets via a tethered charger. The MEMS Fuel Cell represents a disruptive power source technology that can avoid many of these problems. It uses easy-to-store liquid fuels such as methanol and provides more than three times the operating time ...
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| 04/22/2011 |
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Method and Apparatus for In-Situ Real Time Characterization of Energy Storage and Energy Conversion Devices
INL has developed a method and apparatus for determining an impedance of an energy-output device using a random noise stimulus applied to the energy-output device. A random noise signal is generated and converted to a random noise stimulus as a current source correlated to the random noise signal. A bias-reduced response of the energy-output device to the random noise stimulus is generated by comparing a voltage at the energy-output device terminal to an average voltage signal. The random noise...
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| 04/14/2011 |
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High Performance Binderless Electrodes for Rechargeable Lithium Batteries
Portable electronic applications including cell phones, laptop computers, as well as electric vehicles or hybrid electric vehicles require dependable rechargeable batteries. The lithium ion (Li-ion) battery is the preferred source for portable energy storage due to its desirable energy to weight ratio. The materials used in the development of anodes, cathodes and electrolytes are directly responsible for the performance characteristics of Li-ion batteries. In order to meet...
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| 03/31/2011 |
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Battery Life Estimation (BLE) and Data Analysis
Argonne’s BLE Software is a state-of-the-art analytical tool for predicting cell and battery lifetimes on the basis of limited test data. Because hybrid vehicles are so new to the market, researchers don't have data spanning many years. They need a tool to reliably, quickly and accurately predict battery performance. BLE software can make life-cycle estimates using as little as two years' worth of aging data. With this limited data, researchers can use BLE to estimate how battery...
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| 03/25/2011 |
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Redox Flow Batteries
The need for large, grid-scale electrochemical storage is being realized as a critical part of integrating large quantities of renewable, intermittent generation into the electrical grid. PNNL is investigating a number of potential solutions, but the most promising of them is redox flow batteries because of the relatively low cost of scaling them to large capacities. A redox flow battery is a form of rechargeable battery that can reversibly convert electrical energy into ...
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| 03/11/2011 |
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Platinum-Loading Reduction in PEM Fuel Cells
Platinum, a costly precious metal element, is commonly used in fuel cells to facilitate the split of the hydrogen atom, which enables the membrane within a PEM (proton exchange membrane) fuel cell to generate a charge, and thus generate clean, direct current electricity. In PEM fuel cells, hydrogen at the anode generates electron and protons. The protons migrate through the proton-conducting membrane, and react with reduced oxygen at cathode to create water. Meanwhile, electrons move from anode...
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| 02/08/2011 |
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Lithium Air Electrodes
With the surge in demand for electric vehicles, automotive suppliers and manufacturers are in a race to find cutting edge technologies that deliver more powerful batteries in smaller packages and lower cost – a challenge that researchers at Pacific Northwest National Laboratory have undertaken and remain committed to solving.
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| 02/08/2011 |
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Thermoelectric Ambient Energy Harvester
A novel thermoelectric generator (TEG) design by PNNL allows the conversion of ambient thermal energy into electric power for a variety of low-power uses. These miniature TEGs are able to power wireless sensors and their associated radio frequency transmitters used in a wide range of remote monitoring applications including building energy management, automotive component controls, agricultural monitoring, security surveillance, and wildlife management. |
| 01/14/2011 |
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Hybrid power management system and method
NASA Glenn Research Center (GRC) innovators have developed and patented a unique Hybrid Power Management (HPM) system, integrating diverse power devices in an optimal configuration for space and terrestrial applications. An “ultracapacitor” technology is used to store energy in GRC’s system.
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| 01/04/2011 |
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Deep Sea Hybrid Power Systems for Deep Sea Oil & Gas Recovery
An investment in sub-sea (deep-ocean) hybrid power systems is required to enable off-shore oil and gas exploration and harvesting. Advanced deep-ocean drilling operations, locally powered, will provide access to oil and gas reserves otherwise inaccessible. Such technology will therefore enhance the energy security of the United States. The oil and gas industry is being pushed beneath the surface by economic concerns. According to The Economist (September 8th – 14th 2007), there is a...
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| 12/30/2010 |
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Ultrafine Hydrogen Storage Powders
This invention provides for composition and method of making extremely fine powders for storing hydrogen. |
| 12/16/2010 |
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OLED Deposition Technology
Low-cost processing methods will be required if the small organic molecule materials currently under development for use in organic light-emitting devices (OLEDs) and other electronics are ever to realize widespread commercial application.
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| 12/15/2010 |
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Ultra-stable Gold Nanocatalysts
Gold is inert in large quantities but exhibits surprisingly high catalytic activity when dispersed as small nanoparticles on selected metal oxides. ORNL researchers successfully deposited and stabilized gold nanoparticles on surfaces of rare earth materials, creating ultra-stable gold nanocatalysts that exhibit unprecedented efficiency in industrial oxidation processes. The bottleneck for commercialization of gold catalysts has been problems with critical stability.
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| 12/15/2010 |
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New Ionic Liquids with Diverse Properties
Hundreds of new ionic liquids can be synthesized using a method invented by ORNL researchers. This innovation makes it possible to produce ionic liquids and ionic compounds with a variety of tunable chemical properties, and provides ion liquids that are nonvolatile and nonpolluting. These liquids are important in many scientific research and energy applications, including chemical catalysis and in the design of new ultracapacitors.
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| 12/15/2010 |
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Toughened Graphite Electrode for High Heat Electric Arc Furnaces
A tougher and more resilient graphite electrode was developed at ORNL to melt steel, titanium, and other scrap metal in industrial electric arc furnaces. Researchers invented a carbon fiber-pitch binder composition that is tough enough to avoid recurrent electrode failure in industrial smelting. The technology also reduces the amount of carbon needed in the production process and resolves inefficient dispersion of carbon in current technology. |
| 12/15/2010 |
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Directional Reactive Power Ground Plane Transmission
ORNL researchers have developed a pioneering power alternative to batteries using directional reactive power. Batteries are currently the primary option for powering mobile electronic equipment; however, batteries are heavy and battery life is limited. Reactive power is the phenomenon that occurs when alternating voltage and current are 90 degrees out-of-phase with respect to time. This phenomenon allows electrical transmission on a single wire without a return path.
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| 12/08/2010 |
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Solid Lithium Ion Conducting Electrolytes Suitable for Manufacturing Processes
The lithium ion battery found in electronics like cell phones uses liquid electrolytes associated with shorter battery life; this material is also a safety hazard if it is overheated or overcharged. Batteries with solid lithium ion conducting electrolytes would overcome these limitations, but they have insufficient power to meet device energy requirements at a reasonable cost. Researchers at ORNL invented a method for synthesizing materials from solid state reactions that resolves some of these...
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| 12/08/2010 |
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Glass Capacitor for High-Temperature Applications
To meet the demand for smaller, lighter capacitors that have high energy densities, an ORNL researcher developed a capacitor made of glass rods that is constructed like insulated wire. This device can be used for power factor correction, high-voltage capacitors, power electronic filters, energy storage, and components in electric and hybrid-electric vehicles.
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| 12/08/2010 |
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Clad Fiber Capacitor and Fabrication Method
Using glass and high performance polymer technology, an ORNL researcher developed a method for producing energy storage capacitors with high power density and the ability to operate at high temperatures. Conventional capacitors have low power densities and are limited to low temperature operations.
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| 12/08/2010 |
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Atomic Layer Deposition (ALD) Preparation of Noble Metal Catalysts
Organic pollutants in wastewater streams and volatile organic compounds in the atmosphere have been increasing over the recent decades. Currently, semiconductor photocatalysts such as Titanium Oxide (TiO2), are used to minimize the effects of environmental pollution by detoxifying harmful organic materials. These photocatalysts are activated by UV light and break bonds in the contaminant to make it non-toxic. TiO2 provides many benefits in use, as it is low cost, non-toxic, and has the ability...
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| 12/06/2010 |
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Method to Reduce Camber in Anode-Supported SOFCs
Thermal expansion differences between the porous anode/active anode and dense electrolyte in an anode supported solid oxide fuel cell (SOFC) result in a camber (out of plane deflection) after high-temperature heat treatments. Researchers at PNNL have devised two methods to reduce the camber by applying a symmetrical thermal expansion design to the planar cell assembly. |
| 09/23/2010 |
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Non-Cross-Linked Gel Polymer Electrolytes for Lithium Ion Batteries
Berkeley Lab scientists have invented nanostructured gel polymer electrolytes for lithium ion batteries. The electrolytes have high ionic conductivity, high mechanical strength, and they can be easily and affordably processed for lithium ion batteries.
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| 08/20/2010 |
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Nanostructured Anodes for Lithium-Ion Batteries
Savannah River Nuclear Solutions (SRNS), managing contractor of the Savannah River Site (SRS) for the Department of Energy, has developed new anodes for lithium-ion batteries that are reported to increase the energy density four-fold. It is widely known that the energy capacity of Lithium-Ion batteries is limited by the widely used graphite anode that intercalates lithium ions as LiC6. The theoretical capacity of LiC6 is 372mAh/g. To power an electric car for 300 miles, the energy density has...
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| 08/20/2010 |
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Battery Life Predictor Model
Batteries are one of the leading cost drivers of any electric vehicle project. Current practices require that batteries be oversized by design in order to meet the battery warrantee’s end-of-life (EOL) power and energy requirements. This quickly increases the cost of electric vehicles and can price them out of the realm of consideration for most users. NREL scientists have developed a software model that analyzes the performance of batteries over a lifetime of use in real world...
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| 08/03/2010 |
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High Power Performance Lithium Ion Battery
Gao Liu and colleagues at Berkeley Lab have increased the power performance of lithium ion batteries by over 20 percent by optimizing the ratio of polymer binder to conductive additive (acetylene black) in the cathode. The new electrode compositions also significantly improve mechanical resilience and promise longer cycling lifetimes.
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| 07/28/2010 |
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Lithium-Ion Batteries
Design. Build. Test. Break. Repeat. Developing batteries is an expensive and time-intensive process. Testing costs the automotive industry an estimated $1 million for every 50 battery cycling channels, with additional costs for designing and building prototypes totaling millions of dollars. To reduce this process and associated costs, scientists at NREL have designed computer models to predict thermal, electrical, and electrochemical battery performance. These models are so advanced...
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| 07/28/2010 |
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High Conductivity Single-ion Cross-linked Polymers for Lithium Batteries and Fuel Cells
John Kerr and co-workers at Berkeley Lab have developed single-ion cross-linked comb-branched polymer electrolytes with high conductivity for use as membranes in lithium batteries, fuel cells, and electrochromic windows. Solid polymer electrolyte separators are used in lithium batteries instead of common organic solvents because (1) they are non-volatile, (2) they inhibit the growth of dendrites, the tiny metallic snowflake structures in lithium metal electrodes that lead to battery failure,...
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| 07/28/2010 |
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Graphitized Conductive Carbon Coatings for Composite Electrodes
Robert Kostecki and Marek Marcinek of Lawrence Berkeley National Laboratory have developed a method to improve the performance and operational life of composite electrodes by direct deposition of a continuous, uniform film of graphitic carbon coating on the active materials. |
| 07/28/2010 |
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Fast, Low Cost Method for Manufacturing Porous Structures for Fuel Cells, Catalysts and Filtration
Steve Visco, Craig Jacobson, and Michael Tucker of Berkeley Lab have invented a method for manufacturing porous structures that has advantages over using extractable particulates, pore formers that decompose or burn, tape casting, the replica method, and bubble-forming. |
| 07/28/2010 |
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Ceramic-Metal Composites for Electrodes of Lithium Ion Batteries
Lithium’s high energy density makes it desirable for use in rechargeable batteries, but its tendency to form dendrites has limited its use to primary batteries. This limitation can be addressed by using alloys, but their sticky consistency has proved an obstacle to manufacturing.
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| 06/23/2010 |
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Lower Cost Lithium Ion Batteries From Aluminum Substituted Cathode Materials
Although lithium ion batteries are the most promising candidates for plug-in hybrid electric vehicles, the use of cobalt (Co) in cathode materials yields a high battery cost. Mixed transition metal oxides have been considered to replace the standard LiCoO2 cathode materials, but these variations have negative impacts on performance.
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| 06/23/2010 |
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Self-Regulating, Nonflamable Rechargeable Lithium Batteries
Rechargeable lithium batteries are superior to other rechargeable batteries due to their ability to store more energy per unit size and weight and to operate at higher voltages. The performance of lithium ion batteries available today, however, has been compromised by their tendency to overheat during operation. This condition, called “thermal runaway,” can melt the battery’s lithium metal and, in the most serious cases, result in explosive chemical reactions.
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| 06/23/2010 |
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Nanocomposite Carbon/Tin Anodes for Lithium Ion Batteries
An approach developed by Robert Kostecki and Marek Marcinek of Berkeley Lab has given rise to a new generation of nanostructured carbon-tin films that can be produced quickly, efficiently, and inexpensively. These binderless carbon/tin thin-film anodes provide enhanced charge capacity and excellent cycleability in lithium ion battery systems compared with lithium ion anodes currently on the market.
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| 06/23/2010 |
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CO2 as Cushion Gas for Compressed Air Energy Storage
Compressed Air Energy Storage (CAES) can make intermittent renewable energy options, such as wind and solar energy, more cost-effective by using excess energy generated during peak supply periods to compress air that is then injected into underground storage reservoirs. When needed, the compressed air can be fed into a gas turbine to replace between one-quarter and one-half of the natural gas needed to run the turbine.
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| 06/23/2010 |
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Modular Electromechanical Batteries for Cost-Effective Bulk Storage of Electrical Energy
The Laboratory has several decades of experience in the development of EMBs for specialized (high-power) applications where pulses of electrical power are required, such as are needed to "ride-through" short interruptions of electrical power from the net. In the course of this development some critical technologies, such as low-cost "passive" magnetic bearings and special designs for the generator/motors and the fiber-composite rotors of the EMB were developed. Some of these technologies, such...
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| 02/03/2010 |
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Electrostatic Generator/Motor
A novel electrostatic (E-S) generator/motor has been developed in the course of improving electromechanical battery (flywheel energy-storage) technology for the bulk storage of electricity. Electromagnetic-type generator/motors employed in present-day flywheel energy storage systems fell short of meeting the low parasitic losses and low capital cost requirements associated with bulk energy storage systems. To overcome these limitations a new configuration of the E-S generator/motor was...
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| 02/03/2010 |
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Material Independent Design of Photoluminescent Systems Based on Alignment of Polar Molecules in Charged Surface
A design and method to produce new forms of photoluminescent (PL) matter (whose constituent materials need not be photoluminescent) to form materials useful in bio-imaging, energy storage, composite materials, etc. Non-luminescent particles can be transformed into PL materials with this methodology.
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| 02/03/2010 |
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Mega-Pore Nano-Structured Carbon
Current supercapacitor technologies cannot meet the growing demands for high-power energy storage. Meeting this challenge requires the development of new electrode materials. |
| 02/02/2010 |