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HYDROGEN STORAGE WITH GRAPHITE ANION INTERCALATION COMPOUNDS

United States Patent Application

20080175780
A1
View the Complete Application at the US Patent & Trademark Office
The disclosure relates to a material for reversibly storing and releasing hydrogen comprising graphite or a graphitic structure, for example, comprising an ordered graphite structure of carbon and nitrogen atoms wherein the interlayer and/or interstitial volume is occupied with at least one intercalated anionic species. While any suitable anionic species can be employed, examples of suitable species are at least one of: F.sup.- (fluoride), (C.ident.C).sup.2- (diacetylide), and (N.dbd.C.dbd.N).sup.2-. Desirable anionic species typically have a relatively high charge to volume ratio. The disclosure also relates to a material for reversibly storing and releasing hydrogen comprising ordered graphitic structures comprising at least one member selected from the group of graphite, single walled carbon nanotubes, multiwalled carbon nanotubes, graphite nanofibers, carbon nanohorns, and boron nitride. The carbon materials may incorporate substitutional nitrogen atoms in the graphite lattice at a level ranging from about 1 to about 40 atomic percent.
Pez, Guido Peter (Allentown, PA), Cheng, Hansong (Allentown, PA), Cooper, Alan Charles (Macungie, PA), Foo, Maw Lin (Breinigsville, PA)
AIR PRODUCTS AND CHEMICALS, INC. (Allentown PA)
12/ 015,712
January 17, 2008
STATEMENT REGARDING FEDERALLY SPONSORED RESEARCH OR DEVELOPMENT [0003] The Government has rights in this invention pursuant to Agreement Number DE-FC36-04GO14006 between the Department of Energy and Air Products And Chemicals, Inc.